Methyl N-(4-nitro­phen­yl)carbamate

[O-Ethyl N-(4-nitro­phen­yl)thio­carbam­ato-κS](tri-p-tolyl­phosphine-κP)gold(I)

A nearly linear coordination geometry for Au is found in the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(21)H(21)P)]. The thio-carbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au⋯π contact [Au⋯Cg = 3.351 (5) Å; Cg is the centroid of the aromatic ring].

EXPEDITED CANCER POTENCY VALUES AND NO SIGNIFICANT RISK LEVELS (NSRLs) FOR SIX PROPOSITION 65 CARCINOGENS: CARBAZOLE, MeIQ, MeIQx, METHYL CARBAMATE, 4-N-NITROSOMETHYLAMINO)-1-(3-PYRIDYL)-1 BUTANONE, TRIMETHYL PHOSPHATE

Acute Toxicological Evaluation of Low Dose Methyl 2-benzimidazole Carbamate Fungicide on Male Albino Rats

Background: Methyl 2-benzimidazole carbamate (carbendazim) is a synthetic fungicide used against organisms that cause different types of plant diseases. It is widely used as a preservative in leather, paint, textile, fruit, and paper industry. It is also used as an anticancer drug in clinical medicine. Methods: To evaluate the low dose toxicity of this compound in mammalian tissues, carbend...

Crystal structures of ethyl {2-[4-(4-iso­propyl­phen­yl)thia­zol-2-yl]phen­yl}carbamate and ethyl {2-[4-(3-nitro­phen­yl)thia­zol-2-yl]phen­yl}carbamate

The title compounds, C21H22N2O2S (I) and C18H15N3O4S (II), are structural analogs of the alkaloid Thio-sporine B. Both mol-ecules adopt a near-planar V-shaped conformation, which is consolidated by intra-molecular N-H⋯N and C-H⋯O hydrogen bonds. The crystal structure of (I) consists of mlecular stacks along the a axis, in which the mol-ecules are linked to each other by π(S)⋯π(C) inter-actions....

A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ2 S,S′]zinc(II)]-μ2-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ3 S,S′:N] 4-methyl­pyridine hemisolvate]

The title compound, {[Zn(C9H11N2S2)2]·0.5C6H7N} n , comprises two independent, but chemically similar, Zn[S2CN(Et)CH2py]2 residues and a 4-methyl-pyridine solvent mol-ecule in the asymmetric unit. The Zn-containing units are connected into a one-dimensional coordination polymer (zigzag topology) propagating in the [010] direction, with one di-thio-carbamate ligand bridging in a μ2-κ3 mode, empl...